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ST games were often conversions of Amiga games. Much about this can be found at Atari.ST. The games themselves can be found at Joe's FTP. The best original game was the Thrust-deritave Oids, of which there is a beautiful Mac OSX-version by the original makers. The legendary Robotron clone Robotron-clone Llamatron, by Jeff Minter has its original and best version on the ST as well.
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Emulation is provided by Nostalgia
You need a bios though, Tos, which can be obtained (legally only if you own an ST) here,
World of stuart favourite Dr. A, reviewed the worst ST game ever here